Bis{(1-methylimidazol-2-ylmethyl)[2-(2-pyridyl)ethyl]amine-κ3 N,N′,N′′}zinc(II) bis(hexafluoridophosphate)
نویسندگان
چکیده
Two tridentate N-heterocyclic ligands chelate the Zn(II) atom in the title compound, [Zn(C(12)H(16)N(4))(2)](PF(6))(2), conferring a fac-octa-hedral geometry. The Zn(II) atom lies on a center of inversion. The cation is linked to the anion by an N-H⋯F hydrogen bond.
منابع مشابه
[(4-Methylbenzyl)bis(pyridin-2-ylmethyl)amine-κ3 N,N′,N′′]bis(thiocyanato-κS)copper(II) dichloromethane hemisolvate
The title compound, [Cu(NCS)(2)(C(20)H(21)N(3))]·0.5CH(2)Cl(2), crystallized with two independent complex mol-ecules (A and B) in the asymmetric unit, accompanied by one dichloro-methane solvent mol-ecule. Each Cu(II) atom has a square-pyramidal geometry, being coordinated by five N atoms, three from the (4-methyl-benz-yl)bis-(pyridin-2-ylmeth-yl)amine ligand and two from the thio-cyanate ligan...
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In the crystal structure of the centrosymmetric title compound, [Zn(2)Cl(4)(C(14)H(14)N(4))(2)], the Zn(II) atom is coordinated by two N atoms from two 1,2-bis-(imidazol-1-ylmeth-yl)benzene ligands and two Cl atoms to confer a distorted tetra-hedral geometry at the metal center.
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The potential tridentate Schiff base ligand 2-[1-(2-pyridyl-methyl-imino)eth-yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl-pyrrole with 2-amino-methyl-pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl-amine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(I...
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